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Article: Synthesis and reactivities of trans-dioxoosmium(VI) Schiff-base complexes. X-ray crystal structure of dioxo[N,N′-(1,1,2,2-tetramethylethylene)bis(3-tert- butylsalicylidenaminato)]osmium(VI)

TitleSynthesis and reactivities of trans-dioxoosmium(VI) Schiff-base complexes. X-ray crystal structure of dioxo[N,N′-(1,1,2,2-tetramethylethylene)bis(3-tert- butylsalicylidenaminato)]osmium(VI)
Authors
Issue Date1988
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
Citation
Inorganic Chemistry, 1988, v. 27 n. 2, p. 250-253 How to Cite?
AbstractThe syntheses and redox properties of trans-dioxoosmium(VI) Schiff-base Complexes are described. The crystal structure of trans-[OsVIO2(3-t-Bu-saltmen)] has been determined: C28H38N2O4Os, space group P21/c, a = 11.918 (6) Å, b = 10.416 (1) Å, c = 23.53 (1) Å, β = 102.91 (3)°, Z = 4, R = 0.062 for 3651 observed Mo Kα data. The measured osmyl Os-O bond distances are 1.722 (8) and 1.760 (7) Å; other than this, the molecule conforms well to idealized C2 symmetry. Both electrochemical oxidation and reduction of trans-dioxoosmium(VI) Schiff-base complexes are irreversible in acetonitrile. © 1988 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/167863
ISSN
2015 Impact Factor: 4.82
2015 SCImago Journal Rankings: 1.873
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorChe, CMen_US
dc.contributor.authorCheng, WKen_US
dc.contributor.authorMak, TCWen_US
dc.date.accessioned2012-10-08T03:12:17Z-
dc.date.available2012-10-08T03:12:17Z-
dc.date.issued1988en_US
dc.identifier.citationInorganic Chemistry, 1988, v. 27 n. 2, p. 250-253en_US
dc.identifier.issn0020-1669en_US
dc.identifier.urihttp://hdl.handle.net/10722/167863-
dc.description.abstractThe syntheses and redox properties of trans-dioxoosmium(VI) Schiff-base Complexes are described. The crystal structure of trans-[OsVIO2(3-t-Bu-saltmen)] has been determined: C28H38N2O4Os, space group P21/c, a = 11.918 (6) Å, b = 10.416 (1) Å, c = 23.53 (1) Å, β = 102.91 (3)°, Z = 4, R = 0.062 for 3651 observed Mo Kα data. The measured osmyl Os-O bond distances are 1.722 (8) and 1.760 (7) Å; other than this, the molecule conforms well to idealized C2 symmetry. Both electrochemical oxidation and reduction of trans-dioxoosmium(VI) Schiff-base complexes are irreversible in acetonitrile. © 1988 American Chemical Society.en_US
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/icen_US
dc.relation.ispartofInorganic Chemistryen_US
dc.titleSynthesis and reactivities of trans-dioxoosmium(VI) Schiff-base complexes. X-ray crystal structure of dioxo[N,N′-(1,1,2,2-tetramethylethylene)bis(3-tert- butylsalicylidenaminato)]osmium(VI)en_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/ic00275a007-
dc.identifier.scopuseid_2-s2.0-0347476754en_US
dc.identifier.volume27en_US
dc.identifier.issue2en_US
dc.identifier.spage250en_US
dc.identifier.epage253en_US
dc.identifier.isiWOS:A1988L872100007-
dc.publisher.placeUnited Statesen_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridCheng, WK=7402169559en_US
dc.identifier.scopusauthoridMak, TCW=7401931058en_US

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