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Article: Kinetic studies of the reduction of chloromanganese porphyrin

TitleKinetic studies of the reduction of chloromanganese porphyrin
Authors
KeywordsKinetics
Manganese Porphyrin
Reduction
Issue Date1999
PublisherTaylor & Francis Ltd. The Journal's web site is located at http://www.tandf.co.uk/journals/titles/00958972.asp
Citation
Journal Of Coordination Chemistry, 1999, v. 46 n. 4, p. 453-459 How to Cite?
AbstractThe reduction of manganese(III) porphyrins by hydrazine (L) was investigated by stopped-flow techniques. The mechanism of the reaction has been proposed based on the experimental results; the relationship between pseudo-first-order rate constants with the concentration of L. Calculated activation parameters showed that the pre-equilibrium step was exothermic and the reduction step endothermic. Substituent effects in the phenyl rings on the two steps have been examined.
Persistent Identifierhttp://hdl.handle.net/10722/167811
ISSN
2015 Impact Factor: 1.756
2015 SCImago Journal Rankings: 0.404
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorMu, LJen_US
dc.contributor.authorZhou, Yen_US
dc.contributor.authorLin, Hen_US
dc.contributor.authorHuang, Jen_US
dc.contributor.authorShen, Pen_US
dc.date.accessioned2012-10-08T03:11:54Z-
dc.date.available2012-10-08T03:11:54Z-
dc.date.issued1999en_US
dc.identifier.citationJournal Of Coordination Chemistry, 1999, v. 46 n. 4, p. 453-459en_US
dc.identifier.issn0095-8972en_US
dc.identifier.urihttp://hdl.handle.net/10722/167811-
dc.description.abstractThe reduction of manganese(III) porphyrins by hydrazine (L) was investigated by stopped-flow techniques. The mechanism of the reaction has been proposed based on the experimental results; the relationship between pseudo-first-order rate constants with the concentration of L. Calculated activation parameters showed that the pre-equilibrium step was exothermic and the reduction step endothermic. Substituent effects in the phenyl rings on the two steps have been examined.en_US
dc.languageengen_US
dc.publisherTaylor & Francis Ltd. The Journal's web site is located at http://www.tandf.co.uk/journals/titles/00958972.aspen_US
dc.relation.ispartofJournal of Coordination Chemistryen_US
dc.subjectKineticsen_US
dc.subjectManganese Porphyrinen_US
dc.subjectReductionen_US
dc.titleKinetic studies of the reduction of chloromanganese porphyrinen_US
dc.typeArticleen_US
dc.identifier.emailHuang, J:jshuang@hkucc.hku.hken_US
dc.identifier.authorityHuang, J=rp00709en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1080/00958979908054909-
dc.identifier.scopuseid_2-s2.0-0040680832en_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0040680832&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume46en_US
dc.identifier.issue4en_US
dc.identifier.spage453en_US
dc.identifier.epage459en_US
dc.identifier.isiWOS:000080167200007-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridMu, LJ=7005437525en_US
dc.identifier.scopusauthoridZhou, Y=8047648700en_US
dc.identifier.scopusauthoridLin, H=7405572198en_US
dc.identifier.scopusauthoridHuang, J=7407192639en_US
dc.identifier.scopusauthoridShen, P=7201767682en_US

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