File Download

There are no files associated with this item.

  Links for fulltext
     (May Require Subscription)
Supplementary

Article: A high-valent ruthenium(VI) dioxo cation of 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane

TitleA high-valent ruthenium(VI) dioxo cation of 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane
Authors
Issue Date1985
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
Citation
Inorganic Chemistry, 1985, v. 24 n. 12, p. 1797-1800 How to Cite?
AbstractA high-valent trans-[Ru(TMC)O2]2+ (TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane) cation has been produced from trans-[Ru(TMC)Cl2]+ through H2O2 oxidation. This novel diamagnetic ruthenium(VI) dioxo species has been subjected to detailed spectroscopic and electrochemical characterization. The UV-vis absorption spectra of trans-[Ru(TMC)O2]2+ and the previously reported trans-[Ru(NH3)4O2]2+ exhibit a weak vibronic structured absorption band at ∼390 nm. Cyclic voltammetric and controlled-potential coulometric experiments showed that the reduction of trans-[Ru(TMC)O2]2+ to trans-[Ru(TMC)O-(H2O)]2+ proceeded by a single-step two-electron-transfer process. © 1985 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/167809
ISSN
2015 Impact Factor: 4.82
2015 SCImago Journal Rankings: 1.873
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorChe, CMen_US
dc.contributor.authorWong, KYen_US
dc.contributor.authorPoon, CKen_US
dc.date.accessioned2012-10-08T03:11:53Z-
dc.date.available2012-10-08T03:11:53Z-
dc.date.issued1985en_US
dc.identifier.citationInorganic Chemistry, 1985, v. 24 n. 12, p. 1797-1800en_US
dc.identifier.issn0020-1669en_US
dc.identifier.urihttp://hdl.handle.net/10722/167809-
dc.description.abstractA high-valent trans-[Ru(TMC)O2]2+ (TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane) cation has been produced from trans-[Ru(TMC)Cl2]+ through H2O2 oxidation. This novel diamagnetic ruthenium(VI) dioxo species has been subjected to detailed spectroscopic and electrochemical characterization. The UV-vis absorption spectra of trans-[Ru(TMC)O2]2+ and the previously reported trans-[Ru(NH3)4O2]2+ exhibit a weak vibronic structured absorption band at ∼390 nm. Cyclic voltammetric and controlled-potential coulometric experiments showed that the reduction of trans-[Ru(TMC)O2]2+ to trans-[Ru(TMC)O-(H2O)]2+ proceeded by a single-step two-electron-transfer process. © 1985 American Chemical Society.en_US
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/icen_US
dc.relation.ispartofInorganic Chemistryen_US
dc.titleA high-valent ruthenium(VI) dioxo cation of 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecaneen_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/ic00206a019-
dc.identifier.scopuseid_2-s2.0-0039847092en_US
dc.identifier.volume24en_US
dc.identifier.issue12en_US
dc.identifier.spage1797en_US
dc.identifier.epage1800en_US
dc.identifier.isiWOS:A1985AJS2700019-
dc.publisher.placeUnited Statesen_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridWong, KY=7404760030en_US
dc.identifier.scopusauthoridPoon, CK=7202673504en_US

Export via OAI-PMH Interface in XML Formats


OR


Export to Other Non-XML Formats