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Article: Luminescent homo- and heteropolynuclear platinum(II) chalcogenido aggregates based on [Pt2E2 (P∧N)4] units (E = S, Se)

TitleLuminescent homo- and heteropolynuclear platinum(II) chalcogenido aggregates based on [Pt2E2 (P∧N)4] units (E = S, Se)
Authors
KeywordsChalcogens
Luminescence
Platinum
Selenium
Sulfur
Issue Date2002
PublisherWiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www.wiley-vch.de/home/chemistry
Citation
Chemistry - A European Journal, 2002, v. 8 n. 18, p. 4121-4128 How to Cite?
AbstractA series of homodinuclear platinum(II) complexes containing bridging chalcogenido ligands, [Pt2(μ- E)2(P∧N)4] (P∧N = dppy, E=S (1), Se (2); P∧N = tBu-dppy, E=S (3)) (dppy = 2-(diphenylphosphino)pyridine, tBu-dppy = 4-tert-butyl-2-(diphenylphosphino)pyridine) have been synthesized and characterized. The nucleophilicity of the {Pt2E2} unit towards a number of d10 metal ions and complexes has been demonstrated through the successful isolation of a number of novel heteropolynuclear platinum(II) - copper(I), -silver(I), and -gold(I) complexes: [{Pt2μ3- E)2(dppy)4}2Ag3] (PF6)3 (E = S (4); Se (5)) and [Pt2(dppy)4(μ3-E)2 M2(dppm)]-X2 (E = S, M = Ag, X = BF4 (6); E = S, M = Cu, X = PF6 (7); E = S, M = Au, X = PF6 (8); E = Se, M = Ag, X = PF6 (9); E = Se, M = Au, X = PF6 (10)). Some of them display short metal ⋯ metal contacts. These complexes have been found to possess interesting luminescence properties. Through systematic comparison studies, the emission origin has been probed.
Persistent Identifierhttp://hdl.handle.net/10722/167757
ISSN
2015 Impact Factor: 5.771
2015 SCImago Journal Rankings: 2.323
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorYam, VWWen_HK
dc.contributor.authorYu, KLen_HK
dc.contributor.authorCheng, ECCen_HK
dc.contributor.authorYeung, PKYen_HK
dc.contributor.authorCheung, KKen_HK
dc.contributor.authorZhu, Nen_HK
dc.date.accessioned2012-10-08T03:11:05Z-
dc.date.available2012-10-08T03:11:05Z-
dc.date.issued2002en_HK
dc.identifier.citationChemistry - A European Journal, 2002, v. 8 n. 18, p. 4121-4128en_HK
dc.identifier.issn0947-6539en_HK
dc.identifier.urihttp://hdl.handle.net/10722/167757-
dc.description.abstractA series of homodinuclear platinum(II) complexes containing bridging chalcogenido ligands, [Pt2(μ- E)2(P∧N)4] (P∧N = dppy, E=S (1), Se (2); P∧N = tBu-dppy, E=S (3)) (dppy = 2-(diphenylphosphino)pyridine, tBu-dppy = 4-tert-butyl-2-(diphenylphosphino)pyridine) have been synthesized and characterized. The nucleophilicity of the {Pt2E2} unit towards a number of d10 metal ions and complexes has been demonstrated through the successful isolation of a number of novel heteropolynuclear platinum(II) - copper(I), -silver(I), and -gold(I) complexes: [{Pt2μ3- E)2(dppy)4}2Ag3] (PF6)3 (E = S (4); Se (5)) and [Pt2(dppy)4(μ3-E)2 M2(dppm)]-X2 (E = S, M = Ag, X = BF4 (6); E = S, M = Cu, X = PF6 (7); E = S, M = Au, X = PF6 (8); E = Se, M = Ag, X = PF6 (9); E = Se, M = Au, X = PF6 (10)). Some of them display short metal ⋯ metal contacts. These complexes have been found to possess interesting luminescence properties. Through systematic comparison studies, the emission origin has been probed.en_HK
dc.languageengen_US
dc.publisherWiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www.wiley-vch.de/home/chemistryen_HK
dc.relation.ispartofChemistry - A European Journalen_HK
dc.subjectChalcogensen_HK
dc.subjectLuminescenceen_HK
dc.subjectPlatinumen_HK
dc.subjectSeleniumen_HK
dc.subjectSulfuren_HK
dc.titleLuminescent homo- and heteropolynuclear platinum(II) chalcogenido aggregates based on [Pt2E2 (P∧N)4] units (E = S, Se)en_HK
dc.typeArticleen_HK
dc.identifier.emailYam, VWW: wwyam@hku.hken_HK
dc.identifier.emailZhu, N: nzhu@hkucc.hku.hken_HK
dc.identifier.authorityYam, VWW=rp00822en_HK
dc.identifier.authorityZhu, N=rp00845en_HK
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1002/1521-3765(20020916)8:18<4121::AID-CHEM4121>3.0.CO;2-5en_HK
dc.identifier.pmid12298002-
dc.identifier.scopuseid_2-s2.0-0037120165en_HK
dc.identifier.hkuros76032-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0037120165&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume8en_HK
dc.identifier.issue18en_HK
dc.identifier.spage4121en_HK
dc.identifier.epage4128en_HK
dc.identifier.isiWOS:000178146500004-
dc.publisher.placeGermanyen_HK
dc.identifier.scopusauthoridYam, VWW=18539304700en_HK
dc.identifier.scopusauthoridYu, KL=7403385872en_HK
dc.identifier.scopusauthoridCheng, ECC=7201743424en_HK
dc.identifier.scopusauthoridYeung, PKY=7006727700en_HK
dc.identifier.scopusauthoridCheung, KK=7402406613en_HK
dc.identifier.scopusauthoridZhu, N=7201449530en_HK

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