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Article: Luminescence from the 3P2 state of Tm3+

TitleLuminescence from the 3P2 state of Tm3+
Authors
Issue Date2002
Citation
Journal Of Physical Chemistry B, 2002, v. 106 n. 14, p. 3606-3611 How to Cite?
AbstractUsing various ultraviolet laser excitation lines between 199.8 nm (50 034 cm -1) and 266 nm (37 583 cm -1), emission transitions have been observed and assigned for the first time from the 3P 2 term of Tm 3+, located near 37 500 cm -1. The most intense transitions are to the terminal 3H 6 and 3F 4 states, and are almost entirely vibronic in character for Tm 3+ in elpasolite cubic lattices. In other systems, these transitions may find application in ultraviolet lasers. The interpretation of the 3P 2 → 3H 4 emission transition in Cs 2NaTmCl 6 reveals electron-phonon coupling phenomena analogous to that in the 3H 6 ground state, and which provides the explanation for the enormous deviation between the experimental and calculated energy of the 3H 4 Γ 4 level. We also report the quantum cutting of blue to infrared radiation in Cs 2LiTmCl 6 and the upconversion from 1D 2 to 3P 2 in Cs 2NaTmCl 6.
Persistent Identifierhttp://hdl.handle.net/10722/167749
ISSN
2001 Impact Factor: 3.379
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorTanner, PAen_HK
dc.contributor.authorMak, CSKen_HK
dc.contributor.authorMing Kwok, Wen_HK
dc.contributor.authorPhillips, DLen_HK
dc.contributor.authorJoubert, MFen_HK
dc.date.accessioned2012-10-08T03:10:59Z-
dc.date.available2012-10-08T03:10:59Z-
dc.date.issued2002en_HK
dc.identifier.citationJournal Of Physical Chemistry B, 2002, v. 106 n. 14, p. 3606-3611en_HK
dc.identifier.issn1089-5647en_HK
dc.identifier.urihttp://hdl.handle.net/10722/167749-
dc.description.abstractUsing various ultraviolet laser excitation lines between 199.8 nm (50 034 cm -1) and 266 nm (37 583 cm -1), emission transitions have been observed and assigned for the first time from the 3P 2 term of Tm 3+, located near 37 500 cm -1. The most intense transitions are to the terminal 3H 6 and 3F 4 states, and are almost entirely vibronic in character for Tm 3+ in elpasolite cubic lattices. In other systems, these transitions may find application in ultraviolet lasers. The interpretation of the 3P 2 → 3H 4 emission transition in Cs 2NaTmCl 6 reveals electron-phonon coupling phenomena analogous to that in the 3H 6 ground state, and which provides the explanation for the enormous deviation between the experimental and calculated energy of the 3H 4 Γ 4 level. We also report the quantum cutting of blue to infrared radiation in Cs 2LiTmCl 6 and the upconversion from 1D 2 to 3P 2 in Cs 2NaTmCl 6.en_HK
dc.languageengen_US
dc.relation.ispartofJournal of Physical Chemistry Ben_HK
dc.titleLuminescence from the 3P2 state of Tm3+en_HK
dc.typeArticleen_HK
dc.identifier.emailMak, CSK: cskm@hkucc.hku.hken_HK
dc.identifier.emailPhillips, DL: phillips@hku.hken_HK
dc.identifier.authorityMak, CSK=rp00761en_HK
dc.identifier.authorityPhillips, DL=rp00770en_HK
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/jp0138680en_HK
dc.identifier.scopuseid_2-s2.0-0037061957en_HK
dc.identifier.hkuros73897-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0037061957&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume106en_HK
dc.identifier.issue14en_HK
dc.identifier.spage3606en_HK
dc.identifier.epage3611en_HK
dc.identifier.isiWOS:000175022100016-
dc.identifier.scopusauthoridTanner, PA=7101679850en_HK
dc.identifier.scopusauthoridMak, CSK=8899597100en_HK
dc.identifier.scopusauthoridMing Kwok, W=8089592800en_HK
dc.identifier.scopusauthoridPhillips, DL=7404519365en_HK
dc.identifier.scopusauthoridJoubert, MF=22961598500en_HK

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