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Article: Synthesis and structural characterization of a novel luminescent tetranuclear mixed-metal platimim(II)- Copper (I) complex

TitleSynthesis and structural characterization of a novel luminescent tetranuclear mixed-metal platimim(II)- Copper (I) complex
Authors
Issue Date2001
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallics
Citation
Organometallics, 2001, v. 20 n. 4, p. 721-726 How to Cite?
AbstractA novel tetranuclear mixed-metal platinum(II)-copper(I) complex, [Pt 2(dppm) 2(C≡CPh) 4· {Cu(MeCN)} 2](PF 6) 2, has been synthesized by the reaction of its precursor complex, [Pt 2(dppm) 2(C=CPh) 4], with [Cu(MeCN) 4]PF 6. Their crystal structures and luminescence behavior have been determined. Perturbation of the spectroscopic and emission properties has been accomplished by a change in the Pt⋯Pt distance as well as the π-acceptor ability of the alkynyl unit via Cu(I) coordination. © 2001 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/167685
ISSN
2015 Impact Factor: 4.186
2015 SCImago Journal Rankings: 2.043
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorYam, VWWen_US
dc.contributor.authorYu, KLen_US
dc.contributor.authorWong, KMCen_US
dc.contributor.authorCheung, KKen_US
dc.date.accessioned2012-10-08T03:10:00Z-
dc.date.available2012-10-08T03:10:00Z-
dc.date.issued2001en_US
dc.identifier.citationOrganometallics, 2001, v. 20 n. 4, p. 721-726en_US
dc.identifier.issn0276-7333en_US
dc.identifier.urihttp://hdl.handle.net/10722/167685-
dc.description.abstractA novel tetranuclear mixed-metal platinum(II)-copper(I) complex, [Pt 2(dppm) 2(C≡CPh) 4· {Cu(MeCN)} 2](PF 6) 2, has been synthesized by the reaction of its precursor complex, [Pt 2(dppm) 2(C=CPh) 4], with [Cu(MeCN) 4]PF 6. Their crystal structures and luminescence behavior have been determined. Perturbation of the spectroscopic and emission properties has been accomplished by a change in the Pt⋯Pt distance as well as the π-acceptor ability of the alkynyl unit via Cu(I) coordination. © 2001 American Chemical Society.en_US
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallicsen_US
dc.relation.ispartofOrganometallicsen_US
dc.titleSynthesis and structural characterization of a novel luminescent tetranuclear mixed-metal platimim(II)- Copper (I) complexen_US
dc.typeArticleen_US
dc.identifier.emailYam, VWW:wwyam@hku.hken_US
dc.identifier.emailWong, KMC:wongmc@hku.hken_US
dc.identifier.authorityYam, VWW=rp00822en_US
dc.identifier.authorityWong, KMC=rp00809en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/om000713q-
dc.identifier.scopuseid_2-s2.0-0035250429en_US
dc.identifier.hkuros62526-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0035250429&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume20en_US
dc.identifier.issue4en_US
dc.identifier.spage721en_US
dc.identifier.epage726en_US
dc.identifier.isiWOS:000167135000020-
dc.publisher.placeUnited Statesen_US
dc.identifier.scopusauthoridYam, VWW=18539304700en_US
dc.identifier.scopusauthoridYu, KL=7403385872en_US
dc.identifier.scopusauthoridWong, KMC=8061067200en_US
dc.identifier.scopusauthoridCheung, KK=7402406613en_US

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