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Article: Synthesis and crystal structures of monomeric diamidonickel(II) complexes

TitleSynthesis and crystal structures of monomeric diamidonickel(II) complexes
Authors
KeywordsAmides
Chelates
Magnetic Properties
N Ligands
Nickel
Issue Date2000
PublisherWiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www.eurjic.org
Citation
European Journal Of Inorganic Chemistry, 2000 n. 10, p. 2159-2162 How to Cite?
AbstractThe thermally stable nickel(II) diamides [NiL 2] [L = -N(SiMe 3)(8-C 9H 6N) (1), -N(SitBuMe 2)(8-C 9H 6N) (2)] have been synthesized from the reaction of NiCl 2 with the appropriate lithium amide. X-ray crystallography revealed that the amido ligands bind in a chelating manner, forming a distorted tetrahedral environment around the nickel center. Complexes 1 and 2 have magnetic moments of 3.05 and 2.74 μ(B), respectively, which indicate a d 8 electronic configuration with two unpaired electrons.
Persistent Identifierhttp://hdl.handle.net/10722/167640
ISSN
2015 Impact Factor: 2.686
2015 SCImago Journal Rankings: 1.018
References

 

DC FieldValueLanguage
dc.contributor.authorLee, HKen_US
dc.contributor.authorYu, Pen_US
dc.contributor.authorKui, SCFen_US
dc.contributor.authorZhang, ZYen_US
dc.contributor.authorZhou, ZYen_US
dc.contributor.authorMak, TCWen_US
dc.date.accessioned2012-10-08T03:09:22Z-
dc.date.available2012-10-08T03:09:22Z-
dc.date.issued2000en_US
dc.identifier.citationEuropean Journal Of Inorganic Chemistry, 2000 n. 10, p. 2159-2162en_US
dc.identifier.issn1434-1948en_US
dc.identifier.urihttp://hdl.handle.net/10722/167640-
dc.description.abstractThe thermally stable nickel(II) diamides [NiL 2] [L = -N(SiMe 3)(8-C 9H 6N) (1), -N(SitBuMe 2)(8-C 9H 6N) (2)] have been synthesized from the reaction of NiCl 2 with the appropriate lithium amide. X-ray crystallography revealed that the amido ligands bind in a chelating manner, forming a distorted tetrahedral environment around the nickel center. Complexes 1 and 2 have magnetic moments of 3.05 and 2.74 μ(B), respectively, which indicate a d 8 electronic configuration with two unpaired electrons.en_US
dc.languageengen_US
dc.publisherWiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www.eurjic.orgen_US
dc.relation.ispartofEuropean Journal of Inorganic Chemistryen_US
dc.subjectAmidesen_US
dc.subjectChelatesen_US
dc.subjectMagnetic Propertiesen_US
dc.subjectN Ligandsen_US
dc.subjectNickelen_US
dc.titleSynthesis and crystal structures of monomeric diamidonickel(II) complexesen_US
dc.typeArticleen_US
dc.identifier.emailKui, SCF:stevenku@hku.hken_US
dc.identifier.authorityKui, SCF=rp00715en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1002/1099-0682(200010)2000:10<2159::AID-EJIC2159>3.0.CO;2-2-
dc.identifier.scopuseid_2-s2.0-0033770768en_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0033770768&selection=ref&src=s&origin=recordpageen_US
dc.identifier.issue10en_US
dc.identifier.spage2159en_US
dc.identifier.epage2162en_US
dc.publisher.placeGermanyen_US
dc.identifier.scopusauthoridLee, HK=7501482998en_US
dc.identifier.scopusauthoridYu, P=55223089400en_US
dc.identifier.scopusauthoridKui, SCF=6506763660en_US
dc.identifier.scopusauthoridZhang, ZY=8141639100en_US
dc.identifier.scopusauthoridZhou, ZY=7406096262en_US
dc.identifier.scopusauthoridMak, TCW=7401931058en_US

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