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Article: Nanosecond time-resolved resonance Raman investigation of the T1→Tn transition of 2-bromonaphthalene

TitleNanosecond time-resolved resonance Raman investigation of the T1→Tn transition of 2-bromonaphthalene
Authors
Issue Date1998
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cplett
Citation
Chemical Physics Letters, 1998, v. 290 n. 1-3, p. 24-28 How to Cite?
AbstractWe have obtained nanosecond time-resolved resonance Raman spectra of the T1→Tn transition of 2-bromonaphthalene in methanol solvent. The transient resonance Raman spectra indicate that there are mostly structural changes in the C-C stretch ν5a vibrational coordinate along with a smaller amount of change in the C-Br stretch and C-Br in plane deformation coordinates. This suggests that the T1→Tn transition of 2-bromonaphthalene does not initially excite a directly dissociative triplet state and a predissociative mechanism is probably responsible for the efficient Tn state C-Br bond cleavage found in previous photochemistry studies.
Persistent Identifierhttp://hdl.handle.net/10722/167606
ISSN
2015 Impact Factor: 1.86
2015 SCImago Journal Rankings: 0.757
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorShoute, LCTen_US
dc.contributor.authorPan, DHen_US
dc.contributor.authorPhillips, DLen_US
dc.date.accessioned2012-10-08T03:09:00Z-
dc.date.available2012-10-08T03:09:00Z-
dc.date.issued1998en_US
dc.identifier.citationChemical Physics Letters, 1998, v. 290 n. 1-3, p. 24-28en_US
dc.identifier.issn0009-2614en_US
dc.identifier.urihttp://hdl.handle.net/10722/167606-
dc.description.abstractWe have obtained nanosecond time-resolved resonance Raman spectra of the T1→Tn transition of 2-bromonaphthalene in methanol solvent. The transient resonance Raman spectra indicate that there are mostly structural changes in the C-C stretch ν5a vibrational coordinate along with a smaller amount of change in the C-Br stretch and C-Br in plane deformation coordinates. This suggests that the T1→Tn transition of 2-bromonaphthalene does not initially excite a directly dissociative triplet state and a predissociative mechanism is probably responsible for the efficient Tn state C-Br bond cleavage found in previous photochemistry studies.en_US
dc.languageengen_US
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cpletten_US
dc.relation.ispartofChemical Physics Lettersen_US
dc.titleNanosecond time-resolved resonance Raman investigation of the T1→Tn transition of 2-bromonaphthaleneen_US
dc.typeArticleen_US
dc.identifier.emailPhillips, DL:phillips@hku.hken_US
dc.identifier.authorityPhillips, DL=rp00770en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/S0009-2614(98)00465-5-
dc.identifier.scopuseid_2-s2.0-0032568750en_US
dc.identifier.hkuros33912-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0032568750&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume290en_US
dc.identifier.issue1-3en_US
dc.identifier.spage24en_US
dc.identifier.epage28en_US
dc.identifier.isiWOS:000074466600004-
dc.publisher.placeNetherlandsen_US
dc.identifier.scopusauthoridShoute, LCT=6701331171en_US
dc.identifier.scopusauthoridPan, DH=7202085030en_US
dc.identifier.scopusauthoridPhillips, DL=7404519365en_US

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