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Article: A rearranged hydroperoxide from the reduction of artemisinin

TitleA rearranged hydroperoxide from the reduction of artemisinin
Authors
Issue Date1997
PublisherPergamon. The Journal's web site is located at http://www.elsevier.com/locate/tet
Citation
Tetrahedron, 1997, v. 53 n. 22, p. 7493-7500 How to Cite?
AbstractLithium aluminium hydride reduction of artemisinin produces two unexpected rearrangement products in addition to those reported previously. The structure of the major rearrangement product, a tertiary hydroperoxide, was determined by 2D-NMR and chemical reactions. A mechanism is proposed for this rearrangement, based on the observation that dihydroartemisinin can also be converted into the same hydroperoxide in alkaline solution.
Persistent Identifierhttp://hdl.handle.net/10722/167568
ISSN
2015 Impact Factor: 2.645
2015 SCImago Journal Rankings: 0.991
References

 

DC FieldValueLanguage
dc.contributor.authorSy, LKen_US
dc.contributor.authorHui, SMen_US
dc.contributor.authorCheung, KKen_US
dc.contributor.authorBrown, GDen_US
dc.date.accessioned2012-10-08T03:08:35Z-
dc.date.available2012-10-08T03:08:35Z-
dc.date.issued1997en_US
dc.identifier.citationTetrahedron, 1997, v. 53 n. 22, p. 7493-7500en_US
dc.identifier.issn0040-4020en_US
dc.identifier.urihttp://hdl.handle.net/10722/167568-
dc.description.abstractLithium aluminium hydride reduction of artemisinin produces two unexpected rearrangement products in addition to those reported previously. The structure of the major rearrangement product, a tertiary hydroperoxide, was determined by 2D-NMR and chemical reactions. A mechanism is proposed for this rearrangement, based on the observation that dihydroartemisinin can also be converted into the same hydroperoxide in alkaline solution.en_US
dc.languageengen_US
dc.publisherPergamon. The Journal's web site is located at http://www.elsevier.com/locate/teten_US
dc.relation.ispartofTetrahedronen_US
dc.titleA rearranged hydroperoxide from the reduction of artemisininen_US
dc.typeArticleen_US
dc.identifier.emailSy, LK:sylk@hkucc.hku.hken_US
dc.identifier.authoritySy, LK=rp00784en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/S0040-4020(97)00444-4en_US
dc.identifier.scopuseid_2-s2.0-0030989209en_US
dc.identifier.hkuros25300-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0030989209&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume53en_US
dc.identifier.issue22en_US
dc.identifier.spage7493en_US
dc.identifier.epage7500en_US
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridSy, LK=35874602700en_US
dc.identifier.scopusauthoridHui, SM=7202831749en_US
dc.identifier.scopusauthoridCheung, KK=7402406613en_US
dc.identifier.scopusauthoridBrown, GD=7406468149en_US

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