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Article: Vibrational reorganizational energies of the MLCT transition in Pt(dppm)2(PhC≡C)2 and the MMLCT transition in [Pt2(μ-dppm)2(μ-PhC≡C)(PhC≡C)2]+

TitleVibrational reorganizational energies of the MLCT transition in Pt(dppm)2(PhC≡C)2 and the MMLCT transition in [Pt2(μ-dppm)2(μ-PhC≡C)(PhC≡C)2]+
Authors
Issue Date1996
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cplett
Citation
Chemical Physics Letters, 1996, v. 262 n. 6, p. 699-708 How to Cite?
AbstractWe have obtained resonance Raman spectra including absolute Raman cross section measurements taken with excitation wavelengths within the MLCT absorption band of Pt(dppm)2(PhC≡C)2 and the MMLCT absorption band of [Pt2(μ-dppm)2(μ-PhC≡C)(PhC≡C) 2]+. We have simultaneously modeled the absolute absorption and resonance Raman intensities to obtain an estimate of the vibrational reorganizational energies associated with the MLCT transition of Pt(dppm)2(PhC≡C)2 as well as the homogeneous and inhomogeneous broadening contributions to the absorption band. We compare the experimental resonance Raman spectra of the dimer MMLCT transition to those of the MLCT monomer system.
Persistent Identifierhttp://hdl.handle.net/10722/167558
ISSN
2015 Impact Factor: 1.86
2015 SCImago Journal Rankings: 0.757
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorKwok, WMen_US
dc.contributor.authorPhillips, DLen_US
dc.contributor.authorYeung, PKYen_US
dc.contributor.authorYam, VWWen_US
dc.date.accessioned2012-10-08T03:08:28Z-
dc.date.available2012-10-08T03:08:28Z-
dc.date.issued1996en_US
dc.identifier.citationChemical Physics Letters, 1996, v. 262 n. 6, p. 699-708en_US
dc.identifier.issn0009-2614en_US
dc.identifier.urihttp://hdl.handle.net/10722/167558-
dc.description.abstractWe have obtained resonance Raman spectra including absolute Raman cross section measurements taken with excitation wavelengths within the MLCT absorption band of Pt(dppm)2(PhC≡C)2 and the MMLCT absorption band of [Pt2(μ-dppm)2(μ-PhC≡C)(PhC≡C) 2]+. We have simultaneously modeled the absolute absorption and resonance Raman intensities to obtain an estimate of the vibrational reorganizational energies associated with the MLCT transition of Pt(dppm)2(PhC≡C)2 as well as the homogeneous and inhomogeneous broadening contributions to the absorption band. We compare the experimental resonance Raman spectra of the dimer MMLCT transition to those of the MLCT monomer system.en_US
dc.languageengen_US
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cpletten_US
dc.relation.ispartofChemical Physics Lettersen_US
dc.titleVibrational reorganizational energies of the MLCT transition in Pt(dppm)2(PhC≡C)2 and the MMLCT transition in [Pt2(μ-dppm)2(μ-PhC≡C)(PhC≡C)2]+en_US
dc.typeArticleen_US
dc.identifier.emailPhillips, DL:phillips@hku.hken_US
dc.identifier.emailYam, VWW:wwyam@hku.hken_US
dc.identifier.authorityPhillips, DL=rp00770en_US
dc.identifier.authorityYam, VWW=rp00822en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/S0009-2614(96)01139-6en_US
dc.identifier.scopuseid_2-s2.0-0030606174en_US
dc.identifier.hkuros21544-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0030606174&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume262en_US
dc.identifier.issue6en_US
dc.identifier.spage699en_US
dc.identifier.epage708en_US
dc.identifier.isiWOS:A1996VV28400005-
dc.publisher.placeNetherlandsen_US
dc.identifier.scopusauthoridKwok, WM=7103129332en_US
dc.identifier.scopusauthoridPhillips, DL=7404519365en_US
dc.identifier.scopusauthoridYeung, PKY=7006727700en_US
dc.identifier.scopusauthoridYam, VWW=18539304700en_US

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