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Article: Resonance raman analysis of charge-transfer reorganization energies in a covalent dicyanoethylene-aza-adamantane

TitleResonance raman analysis of charge-transfer reorganization energies in a covalent dicyanoethylene-aza-adamantane
Authors
Issue Date1996
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cplett
Citation
Chemical Physics Letters, 1996, v. 258 n. 1-2, p. 87-93 How to Cite?
AbstractResonance Raman cross sections have been measured for a covalent electron donor-acceptor substituted aza-adamantane. Excitation near the maximum of the strong charge-transfer absorption results in resonance enhancement of a number of Raman fundamentals, overtones, and combination bands. The reorganization energy in each molecular mode and the solvent contribution to the electronic linewidth are determined through quantitative modeling of the absorption, Raman, and fluorescence spectra, which are sensitive to solvent dynamics on different time scales. The results suggest that the solvent-induced broadening in methanol has components that fluctuate on a wide range of timescales.
Persistent Identifierhttp://hdl.handle.net/10722/167557
ISSN
2015 Impact Factor: 1.86
2015 SCImago Journal Rankings: 0.757
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorPhillips, DLen_US
dc.contributor.authorGould, IRen_US
dc.contributor.authorVerhoeven, JWen_US
dc.contributor.authorTittelbachHelmrich, Den_US
dc.contributor.authorMyers, ABen_US
dc.date.accessioned2012-10-08T03:08:28Z-
dc.date.available2012-10-08T03:08:28Z-
dc.date.issued1996en_US
dc.identifier.citationChemical Physics Letters, 1996, v. 258 n. 1-2, p. 87-93en_US
dc.identifier.issn0009-2614en_US
dc.identifier.urihttp://hdl.handle.net/10722/167557-
dc.description.abstractResonance Raman cross sections have been measured for a covalent electron donor-acceptor substituted aza-adamantane. Excitation near the maximum of the strong charge-transfer absorption results in resonance enhancement of a number of Raman fundamentals, overtones, and combination bands. The reorganization energy in each molecular mode and the solvent contribution to the electronic linewidth are determined through quantitative modeling of the absorption, Raman, and fluorescence spectra, which are sensitive to solvent dynamics on different time scales. The results suggest that the solvent-induced broadening in methanol has components that fluctuate on a wide range of timescales.en_US
dc.languageengen_US
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cpletten_US
dc.relation.ispartofChemical Physics Lettersen_US
dc.titleResonance raman analysis of charge-transfer reorganization energies in a covalent dicyanoethylene-aza-adamantaneen_US
dc.typeArticleen_US
dc.identifier.emailPhillips, DL:phillips@hku.hken_US
dc.identifier.authorityPhillips, DL=rp00770en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/0009-2614(96)00621-5-
dc.identifier.scopuseid_2-s2.0-0030576397en_US
dc.identifier.hkuros21548-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0030576397&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume258en_US
dc.identifier.issue1-2en_US
dc.identifier.spage87en_US
dc.identifier.epage93en_US
dc.identifier.isiWOS:A1996VB49400013-
dc.publisher.placeNetherlandsen_US
dc.identifier.scopusauthoridPhillips, DL=7404519365en_US
dc.identifier.scopusauthoridGould, IR=36707470300en_US
dc.identifier.scopusauthoridVerhoeven, JW=7102915500en_US
dc.identifier.scopusauthoridTittelbachHelmrich, D=15076265700en_US
dc.identifier.scopusauthoridMyers, AB=7202743342en_US

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