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Article: Studies of the kinetics of the lithium/aluminium electrode in molten LiCl-KCl by linear sweep voltammetry

TitleStudies of the kinetics of the lithium/aluminium electrode in molten LiCl-KCl by linear sweep voltammetry
Authors
Issue Date1982
PublisherSpringer Verlag Dordrecht. The Journal's web site is located at http://springerlink.metapress.com/openurl.asp?genre=journal&issn=0021-891X
Citation
Journal Of Applied Electrochemistry, 1982, v. 12 n. 6, p. 669-680 How to Cite?
AbstractThe deposition of lithium on aluminium leads initially to the formation of a solid solution, followed by the precipitation of various lithium/aluminium alloys. Several fundamental phenomena such as monolayer formation and nucleation were shown to affect the kinetics of the deposition process. In the present investigation, the cyclic voltammetric technique (fast) was used to study these phenomena. It is a very useful technique for the qualitative understanding of the deposition process and in its scanning coulometric modification, which is also utilised in this investigation, it can provide useful semiquantitative information. Voltammetric profiles corresponding to the formation of the α-phase (a solid solution of Li and Al), the β-phase (LiAl) and the γ-phase (Li 3Al) amongst others, were identified and their characteristics investigated. The results are discussed against the background of the possible vitiating effects of impurities in the present paper. © 1982 Chapman and Hall Ltd.
Persistent Identifierhttp://hdl.handle.net/10722/167453
ISSN
2015 Impact Factor: 2.223
2015 SCImago Journal Rankings: 0.676
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorFung, YSen_US
dc.contributor.authorInman, Den_US
dc.contributor.authorWhite, SHen_US
dc.date.accessioned2012-10-08T03:07:12Z-
dc.date.available2012-10-08T03:07:12Z-
dc.date.issued1982en_US
dc.identifier.citationJournal Of Applied Electrochemistry, 1982, v. 12 n. 6, p. 669-680en_US
dc.identifier.issn0021-891Xen_US
dc.identifier.urihttp://hdl.handle.net/10722/167453-
dc.description.abstractThe deposition of lithium on aluminium leads initially to the formation of a solid solution, followed by the precipitation of various lithium/aluminium alloys. Several fundamental phenomena such as monolayer formation and nucleation were shown to affect the kinetics of the deposition process. In the present investigation, the cyclic voltammetric technique (fast) was used to study these phenomena. It is a very useful technique for the qualitative understanding of the deposition process and in its scanning coulometric modification, which is also utilised in this investigation, it can provide useful semiquantitative information. Voltammetric profiles corresponding to the formation of the α-phase (a solid solution of Li and Al), the β-phase (LiAl) and the γ-phase (Li 3Al) amongst others, were identified and their characteristics investigated. The results are discussed against the background of the possible vitiating effects of impurities in the present paper. © 1982 Chapman and Hall Ltd.en_US
dc.languageengen_US
dc.publisherSpringer Verlag Dordrecht. The Journal's web site is located at http://springerlink.metapress.com/openurl.asp?genre=journal&issn=0021-891Xen_US
dc.relation.ispartofJournal of Applied Electrochemistryen_US
dc.titleStudies of the kinetics of the lithium/aluminium electrode in molten LiCl-KCl by linear sweep voltammetryen_US
dc.typeArticleen_US
dc.identifier.emailFung, YS:ysfung@hku.hken_US
dc.identifier.authorityFung, YS=rp00697en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1007/BF00617487en_US
dc.identifier.scopuseid_2-s2.0-0020203542en_US
dc.identifier.volume12en_US
dc.identifier.issue6en_US
dc.identifier.spage669en_US
dc.identifier.epage680en_US
dc.identifier.isiWOS:A1982PP17800005-
dc.publisher.placeNetherlandsen_US
dc.identifier.scopusauthoridFung, YS=13309754700en_US
dc.identifier.scopusauthoridInman, D=7101824284en_US
dc.identifier.scopusauthoridWhite, SH=7404080545en_US

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