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Article: Low-spin iron(III) complexes of a tetradentate bis-amide ligand and X-ray crystal structure of trans-[Fe(bpc)(1-MeIm)2]ClO4 (H2bpc=4, 5-dichloro-1, 2-bis(2-pyridinecarboxamido)benzene; 1-MeIm=1-methylimidazole)

TitleLow-spin iron(III) complexes of a tetradentate bis-amide ligand and X-ray crystal structure of trans-[Fe(bpc)(1-MeIm)2]ClO4 (H2bpc=4, 5-dichloro-1, 2-bis(2-pyridinecarboxamido)benzene; 1-MeIm=1-methylimidazole)
Authors
Issue Date1992
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/ica
Citation
Inorganica Chimica Acta, 1992, v. 196 n. 1, p. 43-48 How to Cite?
AbstractA series of low-spin iron(III) complexes [Fe(bpc)(L)2]+ (H2bpc=4,5-dichloro-1,2-bis(2-pyridinecarboxamido)- benzene; LBu3P, Im, 1-MeIm, tBupy) have been synthesized. These iron complexes display reversible one-electron oxidation and reduction couples. The stable one-electron-oxidized species [Fe(bpc)(Bu3P)2]2+ has been generated electrochemically. The complex trans-[Fe(bpc)(1-MeIm)2](ClO4) has been characterized by X-ray crystallography: space group P1; a=8.425(1), b=9.512(1), c=18.413(19) Å; α=96.91(4), β=95.83(4), γ=90.44(1)°; V=1457(2) Å3; Z=2. © 1992.
Persistent Identifierhttp://hdl.handle.net/10722/167369
ISSN
2015 Impact Factor: 1.918
2015 SCImago Journal Rankings: 0.584
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorChe, CMen_US
dc.contributor.authorLeung, WHen_US
dc.contributor.authorLi, CKen_US
dc.contributor.authorHeiYing, Cen_US
dc.contributor.authorShieMing, Pen_US
dc.date.accessioned2012-10-08T03:06:08Z-
dc.date.available2012-10-08T03:06:08Z-
dc.date.issued1992en_US
dc.identifier.citationInorganica Chimica Acta, 1992, v. 196 n. 1, p. 43-48en_US
dc.identifier.issn0020-1693en_US
dc.identifier.urihttp://hdl.handle.net/10722/167369-
dc.description.abstractA series of low-spin iron(III) complexes [Fe(bpc)(L)2]+ (H2bpc=4,5-dichloro-1,2-bis(2-pyridinecarboxamido)- benzene; LBu3P, Im, 1-MeIm, tBupy) have been synthesized. These iron complexes display reversible one-electron oxidation and reduction couples. The stable one-electron-oxidized species [Fe(bpc)(Bu3P)2]2+ has been generated electrochemically. The complex trans-[Fe(bpc)(1-MeIm)2](ClO4) has been characterized by X-ray crystallography: space group P1; a=8.425(1), b=9.512(1), c=18.413(19) Å; α=96.91(4), β=95.83(4), γ=90.44(1)°; V=1457(2) Å3; Z=2. © 1992.en_US
dc.languageengen_US
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/icaen_US
dc.relation.ispartofInorganica Chimica Actaen_US
dc.titleLow-spin iron(III) complexes of a tetradentate bis-amide ligand and X-ray crystal structure of trans-[Fe(bpc)(1-MeIm)2]ClO4 (H2bpc=4, 5-dichloro-1, 2-bis(2-pyridinecarboxamido)benzene; 1-MeIm=1-methylimidazole)en_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/S0020-1693(00)82958-8-
dc.identifier.scopuseid_2-s2.0-0002630035en_US
dc.identifier.volume196en_US
dc.identifier.issue1en_US
dc.identifier.spage43en_US
dc.identifier.epage48en_US
dc.identifier.isiWOS:A1992JL78200006-
dc.publisher.placeNetherlandsen_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridLeung, WH=7201504510en_US
dc.identifier.scopusauthoridLi, CK=8714186500en_US
dc.identifier.scopusauthoridHeiYing, C=24320664200en_US
dc.identifier.scopusauthoridShieMing, P=24286339000en_US

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