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Article: Resonance Raman intensity analysis investigation of metal-metal bonded transitions: An examination of the1A2u ← 1A1g (5dσ* → 6pσ) transition of Pt2(P2O5H2)4 4-

TitleResonance Raman intensity analysis investigation of metal-metal bonded transitions: An examination of the1A2u ← 1A1g (5dσ* → 6pσ) transition of Pt2(P2O5H2)4 4-
Authors
Issue Date1999
PublisherJohn Wiley & Sons Ltd. The Journal's web site is located at http://www3.interscience.wiley.com/cgi-bin/jhome/3420
Citation
Journal Of Raman Spectroscopy, 1999, v. 30 n. 11, p. 987-993 How to Cite?
AbstractA preliminary resonance Raman intensity analysis study of the 1A2u ← 1A1g (5dσ* → 6pσ) transition of (n-Bu4N)4[Pt2(P2O5H 2)4] in acetonitrile solution at room temperature is reported. The absolute resonance Raman and absorption intensities were simultaneously simulated using wavepacket calculations and a simple model. The best fit parameters indicate that the Pt - Pt bond length changes by about 0.225 Å in the initially excited 1A2u state relative to the ground state. This is in good agreement with previous studies on the vibronically structured absorption and emission spectra of low-temperature crystalline (n-Bu4N)4[Pt2(P2O5H 2)4] which suggested that the Pt - Pt bond length changes by about 0.21 Å in the 1,3A2u states. The resonance Raman intensity analysis demonstrated here can be generally applied to metal-metal bonded electronic transitions for compounds and sample conditions (such as room temperature liquids for many samples) which do not exhibit any vibronic structure. Copyright © 1999 John Wiley & Sons, Ltd.
Persistent Identifierhttp://hdl.handle.net/10722/167364
ISSN
2015 Impact Factor: 2.395
2015 SCImago Journal Rankings: 1.075
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorLeung, KHen_US
dc.contributor.authorPhillips, DLen_US
dc.contributor.authorChe, CMen_US
dc.contributor.authorMiskowski, VMen_US
dc.date.accessioned2012-10-08T03:06:04Z-
dc.date.available2012-10-08T03:06:04Z-
dc.date.issued1999en_US
dc.identifier.citationJournal Of Raman Spectroscopy, 1999, v. 30 n. 11, p. 987-993en_US
dc.identifier.issn0377-0486en_US
dc.identifier.urihttp://hdl.handle.net/10722/167364-
dc.description.abstractA preliminary resonance Raman intensity analysis study of the 1A2u ← 1A1g (5dσ* → 6pσ) transition of (n-Bu4N)4[Pt2(P2O5H 2)4] in acetonitrile solution at room temperature is reported. The absolute resonance Raman and absorption intensities were simultaneously simulated using wavepacket calculations and a simple model. The best fit parameters indicate that the Pt - Pt bond length changes by about 0.225 Å in the initially excited 1A2u state relative to the ground state. This is in good agreement with previous studies on the vibronically structured absorption and emission spectra of low-temperature crystalline (n-Bu4N)4[Pt2(P2O5H 2)4] which suggested that the Pt - Pt bond length changes by about 0.21 Å in the 1,3A2u states. The resonance Raman intensity analysis demonstrated here can be generally applied to metal-metal bonded electronic transitions for compounds and sample conditions (such as room temperature liquids for many samples) which do not exhibit any vibronic structure. Copyright © 1999 John Wiley & Sons, Ltd.en_US
dc.languageengen_US
dc.publisherJohn Wiley & Sons Ltd. The Journal's web site is located at http://www3.interscience.wiley.com/cgi-bin/jhome/3420en_US
dc.relation.ispartofJournal of Raman Spectroscopyen_US
dc.titleResonance Raman intensity analysis investigation of metal-metal bonded transitions: An examination of the1A2u ← 1A1g (5dσ* → 6pσ) transition of Pt2(P2O5H2)4 4-en_US
dc.typeArticleen_US
dc.identifier.emailPhillips, DL:phillips@hku.hken_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityPhillips, DL=rp00770en_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1002/(SICI)1097-4555(199911)30:11<987::AID-JRS471>3.0.CO;2-3-
dc.identifier.scopuseid_2-s2.0-0001768169en_US
dc.identifier.hkuros50351-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0001768169&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume30en_US
dc.identifier.issue11en_US
dc.identifier.spage987en_US
dc.identifier.epage993en_US
dc.identifier.isiWOS:000083721900003-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridLeung, KH=7401860609en_US
dc.identifier.scopusauthoridPhillips, DL=7404519365en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridMiskowski, VM=6603008214en_US

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