File Download

There are no files associated with this item.

  Links for fulltext
     (May Require Subscription)
Supplementary

Article: Synthesis, Spectroscopic Properties, and Reactivities of Bis(tosylimido)osmium(VI) Porphyrin Complexes. X-ray Crystal Structure of [OsVI(TPP)(NSO2C6H4-pCH 3)2] (TPP = Tetraphenylporphyrinato)

TitleSynthesis, Spectroscopic Properties, and Reactivities of Bis(tosylimido)osmium(VI) Porphyrin Complexes. X-ray Crystal Structure of [OsVI(TPP)(NSO2C6H4-pCH 3)2] (TPP = Tetraphenylporphyrinato)
Authors
Issue Date1998
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
Citation
Inorganic Chemistry, 1998, v. 37 n. 26, p. 6564-6567 How to Cite?
AbstractThe bis(tosylimido)osmium(VI) porphyrins [OsVI(Por)(NTs)2] [Por = tetraphenylporphyrinato (TPP), meso-tetrakis(p-tolyl)porphyrinato (TTP), meso-tetrakis(4-chlorophenyl)porphyrinato (4-Cl-TPP), weso-tetrakis(4-methoxyphenyl)porphyrinato (4-MeO-TPP); Ts = tosyl] were prepared from the reactions of [OsII(Por)(CO)(MeOH)] with excess PhI=NTs in dichloromethane. The X-ray crystal structure of [OsVI(TPP)(NTs)2] has been determined. Crystal data for [OsVI(TPP)(NTs)2]: triclinic, space group P1̄ (No. 2), a = 10.836(3) Å, b = 12.067(4) Å, c = 19.647(6) Å, α = 94.05(3)°, β= 93.88(3)°, γ = 104.65(3)°, V = 2469(1) Å3, Z = 2, R (Rw) = 0.030 (0.038), goodness-of-fit =1.19. The mean Os=NTs distance is 1.800 Å. The Os-N-S angles average 155.8°. Reaction of [OsVI(TPP)(NTs)2] with triphenylphosphine gives Ph3P=NTs and [OsII(TPP)(PPh3)2].
Persistent Identifierhttp://hdl.handle.net/10722/167282
ISSN
2015 Impact Factor: 4.82
2015 SCImago Journal Rankings: 1.873
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorAu, SMen_US
dc.contributor.authorFung, WHen_US
dc.contributor.authorHuang, JSen_US
dc.contributor.authorCheung, KKen_US
dc.contributor.authorChe, CMen_US
dc.date.accessioned2012-10-08T03:05:13Z-
dc.date.available2012-10-08T03:05:13Z-
dc.date.issued1998en_US
dc.identifier.citationInorganic Chemistry, 1998, v. 37 n. 26, p. 6564-6567en_US
dc.identifier.issn0020-1669en_US
dc.identifier.urihttp://hdl.handle.net/10722/167282-
dc.description.abstractThe bis(tosylimido)osmium(VI) porphyrins [OsVI(Por)(NTs)2] [Por = tetraphenylporphyrinato (TPP), meso-tetrakis(p-tolyl)porphyrinato (TTP), meso-tetrakis(4-chlorophenyl)porphyrinato (4-Cl-TPP), weso-tetrakis(4-methoxyphenyl)porphyrinato (4-MeO-TPP); Ts = tosyl] were prepared from the reactions of [OsII(Por)(CO)(MeOH)] with excess PhI=NTs in dichloromethane. The X-ray crystal structure of [OsVI(TPP)(NTs)2] has been determined. Crystal data for [OsVI(TPP)(NTs)2]: triclinic, space group P1̄ (No. 2), a = 10.836(3) Å, b = 12.067(4) Å, c = 19.647(6) Å, α = 94.05(3)°, β= 93.88(3)°, γ = 104.65(3)°, V = 2469(1) Å3, Z = 2, R (Rw) = 0.030 (0.038), goodness-of-fit =1.19. The mean Os=NTs distance is 1.800 Å. The Os-N-S angles average 155.8°. Reaction of [OsVI(TPP)(NTs)2] with triphenylphosphine gives Ph3P=NTs and [OsII(TPP)(PPh3)2].en_US
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/icen_US
dc.relation.ispartofInorganic Chemistryen_US
dc.titleSynthesis, Spectroscopic Properties, and Reactivities of Bis(tosylimido)osmium(VI) Porphyrin Complexes. X-ray Crystal Structure of [OsVI(TPP)(NSO2C6H4-pCH 3)2] (TPP = Tetraphenylporphyrinato)en_US
dc.typeArticleen_US
dc.identifier.emailHuang, JS:jshuang@hkucc.hku.hken_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityHuang, JS=rp00709en_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/ic980256u-
dc.identifier.pmid11670787-
dc.identifier.scopuseid_2-s2.0-0000601741en_US
dc.identifier.hkuros40279-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0000601741&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume37en_US
dc.identifier.issue26en_US
dc.identifier.spage6564en_US
dc.identifier.epage6567en_US
dc.identifier.isiWOS:000077839100006-
dc.publisher.placeUnited Statesen_US
dc.identifier.scopusauthoridAu, SM=7005457811en_US
dc.identifier.scopusauthoridFung, WH=7102150303en_US
dc.identifier.scopusauthoridHuang, JS=7407192639en_US
dc.identifier.scopusauthoridCheung, KK=7402406613en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US

Export via OAI-PMH Interface in XML Formats


OR


Export to Other Non-XML Formats