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Article: Resonance raman investigation of the Au(I) - Au(I) interaction of the 1[dσ*pσ] Excited state of Au2(dcpm)2(ClO4)2 (dcpm = bis(dicyclohexylphosphine)methane)

TitleResonance raman investigation of the Au(I) - Au(I) interaction of the 1[dσ*pσ] Excited state of Au2(dcpm)2(ClO4)2 (dcpm = bis(dicyclohexylphosphine)methane)
Authors
Issue Date1999
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.html
Citation
Journal Of The American Chemical Society, 1999, v. 121 n. 20, p. 4799-4803 How to Cite?
AbstractWe present a resonance Raman investigation of the lowest energy dipole- allowed absorption band of [Au2(dcpm)2](ClO4)2 (dcpm = bis(dicyclohexylphosphine)methane). The resonance Raman spectra provide the first experimental proof of the 5dσ*→6pσ electronic transition in dinuclear gold(I)-phosphine compounds. A resonance Raman intensity analysis of the spectra allows estimation of the structural changes of the [dσ*pσ] excited states relative to the ground state.
Persistent Identifierhttp://hdl.handle.net/10722/167277
ISSN
2015 Impact Factor: 13.038
2015 SCImago Journal Rankings: 7.123
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorLeung, KHen_US
dc.contributor.authorPhillips, DLen_US
dc.contributor.authorTse, MCen_US
dc.contributor.authorChe, CMen_US
dc.contributor.authorMiskowski, VMen_US
dc.date.accessioned2012-10-08T03:05:10Z-
dc.date.available2012-10-08T03:05:10Z-
dc.date.issued1999en_US
dc.identifier.citationJournal Of The American Chemical Society, 1999, v. 121 n. 20, p. 4799-4803en_US
dc.identifier.issn0002-7863en_US
dc.identifier.urihttp://hdl.handle.net/10722/167277-
dc.description.abstractWe present a resonance Raman investigation of the lowest energy dipole- allowed absorption band of [Au2(dcpm)2](ClO4)2 (dcpm = bis(dicyclohexylphosphine)methane). The resonance Raman spectra provide the first experimental proof of the 5dσ*→6pσ electronic transition in dinuclear gold(I)-phosphine compounds. A resonance Raman intensity analysis of the spectra allows estimation of the structural changes of the [dσ*pσ] excited states relative to the ground state.en_US
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.htmlen_US
dc.relation.ispartofJournal of the American Chemical Societyen_US
dc.titleResonance raman investigation of the Au(I) - Au(I) interaction of the 1[dσ*pσ] Excited state of Au2(dcpm)2(ClO4)2 (dcpm = bis(dicyclohexylphosphine)methane)en_US
dc.typeArticleen_US
dc.identifier.emailPhillips, DL:phillips@hku.hken_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityPhillips, DL=rp00770en_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/ja990195een_US
dc.identifier.scopuseid_2-s2.0-0000485387en_US
dc.identifier.hkuros43791-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0000485387&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume121en_US
dc.identifier.issue20en_US
dc.identifier.spage4799en_US
dc.identifier.epage4803en_US
dc.identifier.isiWOS:000080646000009-
dc.publisher.placeUnited Statesen_US
dc.identifier.scopusauthoridLeung, KH=7401860609en_US
dc.identifier.scopusauthoridPhillips, DL=7404519365en_US
dc.identifier.scopusauthoridTse, MC=7103352654en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridMiskowski, VM=6603008214en_US

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