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- Publisher Website: 10.1016/S0277-5387(00)83415-4
- Scopus: eid_2-s2.0-0000146227
- WOS: WOS:A1994PU27200005
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Article: Synthesis, redox properties and reactivities of ruthenium(II) complexes of 1,1′-biisoquinoline (BIQN) and X-ray crystal structure of [RuII(terpy)(BIQN)(Cl)]ClO4 (terpy = 2,2′:6′, 2″-terpyridine)
| Title | Synthesis, redox properties and reactivities of ruthenium(II) complexes of 1,1′-biisoquinoline (BIQN) and X-ray crystal structure of [RuII(terpy)(BIQN)(Cl)]ClO4 (terpy = 2,2′:6′, 2″-terpyridine) |
|---|---|
| Authors | |
| Issue Date | 1994 |
| Publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly |
| Citation | Polyhedron, 1994, v. 13 n. 21, p. 2963-2969 How to Cite? |
| Abstract | The syntheses of the complexes [RuII(terpy)(BIQN)Cl]ClO4 (1) and [RuII (terpy)(BIQN)(OH2)](ClO4)2 (2) are described. The structure of 1 has been established by X-ray crystallography. The dihedral angle between the two isoquinoline rings is 37.4°. In aqueous solution, [RuII(terpy)(BIQN)(OH2)](ClO4)2 shows two reversible/quasi-reversible oxidation couples assigned to the oxidation of ruthenium(II) to ruthenium(III) and ruthenium(III) to ruthenium(IV). [RuII(terpy)(BIQN)(OH2)](ClO4)2 is an active catalyst for the oxidation of alkenes by PhIO. © 1994. |
| Persistent Identifier | http://hdl.handle.net/10722/167255 |
| ISSN | 2021 Impact Factor: 2.975 2020 SCImago Journal Rankings: 0.496 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Yu, WY | en_US |
| dc.contributor.author | Cheng, WC | en_US |
| dc.contributor.author | Che, CM | en_US |
| dc.contributor.author | Wang, Y | en_US |
| dc.date.accessioned | 2012-10-08T03:04:56Z | - |
| dc.date.available | 2012-10-08T03:04:56Z | - |
| dc.date.issued | 1994 | en_US |
| dc.identifier.citation | Polyhedron, 1994, v. 13 n. 21, p. 2963-2969 | en_US |
| dc.identifier.issn | 0277-5387 | en_US |
| dc.identifier.uri | http://hdl.handle.net/10722/167255 | - |
| dc.description.abstract | The syntheses of the complexes [RuII(terpy)(BIQN)Cl]ClO4 (1) and [RuII (terpy)(BIQN)(OH2)](ClO4)2 (2) are described. The structure of 1 has been established by X-ray crystallography. The dihedral angle between the two isoquinoline rings is 37.4°. In aqueous solution, [RuII(terpy)(BIQN)(OH2)](ClO4)2 shows two reversible/quasi-reversible oxidation couples assigned to the oxidation of ruthenium(II) to ruthenium(III) and ruthenium(III) to ruthenium(IV). [RuII(terpy)(BIQN)(OH2)](ClO4)2 is an active catalyst for the oxidation of alkenes by PhIO. © 1994. | en_US |
| dc.language | eng | en_US |
| dc.publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly | en_US |
| dc.relation.ispartof | Polyhedron | en_US |
| dc.title | Synthesis, redox properties and reactivities of ruthenium(II) complexes of 1,1′-biisoquinoline (BIQN) and X-ray crystal structure of [RuII(terpy)(BIQN)(Cl)]ClO4 (terpy = 2,2′:6′, 2″-terpyridine) | en_US |
| dc.type | Article | en_US |
| dc.identifier.email | Che, CM:cmche@hku.hk | en_US |
| dc.identifier.authority | Che, CM=rp00670 | en_US |
| dc.description.nature | link_to_subscribed_fulltext | en_US |
| dc.identifier.doi | 10.1016/S0277-5387(00)83415-4 | - |
| dc.identifier.scopus | eid_2-s2.0-0000146227 | en_US |
| dc.identifier.hkuros | 1471 | - |
| dc.identifier.volume | 13 | en_US |
| dc.identifier.issue | 21 | en_US |
| dc.identifier.spage | 2963 | en_US |
| dc.identifier.epage | 2969 | en_US |
| dc.identifier.isi | WOS:A1994PU27200005 | - |
| dc.publisher.place | Netherlands | en_US |
| dc.identifier.scopusauthorid | Yu, WY=7403913673 | en_US |
| dc.identifier.scopusauthorid | Cheng, WC=7402169293 | en_US |
| dc.identifier.scopusauthorid | Che, CM=7102442791 | en_US |
| dc.identifier.scopusauthorid | Wang, Y=36072665800 | en_US |
| dc.identifier.issnl | 0277-5387 | - |