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Article: Synthesis, redox properties and reactivities of ruthenium(II) complexes of 1,1′-biisoquinoline (BIQN) and X-ray crystal structure of [RuII(terpy)(BIQN)(Cl)]ClO4 (terpy = 2,2′:6′, 2″-terpyridine)

TitleSynthesis, redox properties and reactivities of ruthenium(II) complexes of 1,1′-biisoquinoline (BIQN) and X-ray crystal structure of [RuII(terpy)(BIQN)(Cl)]ClO4 (terpy = 2,2′:6′, 2″-terpyridine)
Authors
Issue Date1994
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly
Citation
Polyhedron, 1994, v. 13 n. 21, p. 2963-2969 How to Cite?
AbstractThe syntheses of the complexes [RuII(terpy)(BIQN)Cl]ClO4 (1) and [RuII (terpy)(BIQN)(OH2)](ClO4)2 (2) are described. The structure of 1 has been established by X-ray crystallography. The dihedral angle between the two isoquinoline rings is 37.4°. In aqueous solution, [RuII(terpy)(BIQN)(OH2)](ClO4)2 shows two reversible/quasi-reversible oxidation couples assigned to the oxidation of ruthenium(II) to ruthenium(III) and ruthenium(III) to ruthenium(IV). [RuII(terpy)(BIQN)(OH2)](ClO4)2 is an active catalyst for the oxidation of alkenes by PhIO. © 1994.
Persistent Identifierhttp://hdl.handle.net/10722/167255
ISSN
2015 Impact Factor: 2.108
2015 SCImago Journal Rankings: 0.592
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorYu, WYen_US
dc.contributor.authorCheng, WCen_US
dc.contributor.authorChe, CMen_US
dc.contributor.authorWang, Yen_US
dc.date.accessioned2012-10-08T03:04:56Z-
dc.date.available2012-10-08T03:04:56Z-
dc.date.issued1994en_US
dc.identifier.citationPolyhedron, 1994, v. 13 n. 21, p. 2963-2969en_US
dc.identifier.issn0277-5387en_US
dc.identifier.urihttp://hdl.handle.net/10722/167255-
dc.description.abstractThe syntheses of the complexes [RuII(terpy)(BIQN)Cl]ClO4 (1) and [RuII (terpy)(BIQN)(OH2)](ClO4)2 (2) are described. The structure of 1 has been established by X-ray crystallography. The dihedral angle between the two isoquinoline rings is 37.4°. In aqueous solution, [RuII(terpy)(BIQN)(OH2)](ClO4)2 shows two reversible/quasi-reversible oxidation couples assigned to the oxidation of ruthenium(II) to ruthenium(III) and ruthenium(III) to ruthenium(IV). [RuII(terpy)(BIQN)(OH2)](ClO4)2 is an active catalyst for the oxidation of alkenes by PhIO. © 1994.en_US
dc.languageengen_US
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/polyen_US
dc.relation.ispartofPolyhedronen_US
dc.titleSynthesis, redox properties and reactivities of ruthenium(II) complexes of 1,1′-biisoquinoline (BIQN) and X-ray crystal structure of [RuII(terpy)(BIQN)(Cl)]ClO4 (terpy = 2,2′:6′, 2″-terpyridine)en_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/S0277-5387(00)83415-4-
dc.identifier.scopuseid_2-s2.0-0000146227en_US
dc.identifier.hkuros1471-
dc.identifier.volume13en_US
dc.identifier.issue21en_US
dc.identifier.spage2963en_US
dc.identifier.epage2969en_US
dc.identifier.isiWOS:A1994PU27200005-
dc.publisher.placeNetherlandsen_US
dc.identifier.scopusauthoridYu, WY=7403913673en_US
dc.identifier.scopusauthoridCheng, WC=7402169293en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridWang, Y=36072665800en_US

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