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Article: An unprecedented luminescent polynuclear gold(I) μ3-sulfido cluster with a thiacrown-like architecture

TitleAn unprecedented luminescent polynuclear gold(I) μ3-sulfido cluster with a thiacrown-like architecture
Authors
Issue Date2010
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.html
Citation
Journal Of The American Chemical Society, 2010, v. 132 n. 50, p. 17646-17648 How to Cite?
AbstractAn unprecedented Au 18 thiacrown directed by Au(I) ···Au(I) interactions and supported by tridentate phosphine (dpepp) and μ 3-sulfido ligands that highly resembles the 18-membered thiacrown ether [18]aneS 6 in appearance has been synthesized. The sulfides of the Au 3(μ 3-S) units in the central cavity point toward each other and are located on the same plane, allowing them to bind the soft Ag + ion with immediate and pronounced spectroscopic changes. Reversible binding and spectroscopic changes can be readily achieved upon addition of CH 3CN without disruption of the Au 18 macrocycle. © 2010 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/133588
ISSN
2015 Impact Factor: 13.038
2015 SCImago Journal Rankings: 7.123
ISI Accession Number ID
Funding AgencyGrant Number
University of Hong Kong
University Grants Committee Areas of Excellence SchemeAoE/P-03/08
Research Grants Council of Hong Kong Special Administrative Region, P. R. ChinaHKU 7060/09P
Funding Information:

V.W.-W.Y. acknowledges support from The University of Hong Kong under the Distinguished Research Achievement Award Scheme and T.K.-M.L. the receipt of a postgraduate studentship from The University of Hong Kong. This work was supported by the University Grants Committee Areas of Excellence Scheme (AoE/P-03/08) and a General Research Fund (GRF) Grant from the Research Grants Council of Hong Kong Special Administrative Region, P. R. China (HKU 7060/09P).

References
Grants

 

DC FieldValueLanguage
dc.contributor.authorLee, TKMen_HK
dc.contributor.authorZhu, Nen_HK
dc.contributor.authorYam, VWWen_HK
dc.date.accessioned2011-05-24T02:11:30Z-
dc.date.available2011-05-24T02:11:30Z-
dc.date.issued2010en_HK
dc.identifier.citationJournal Of The American Chemical Society, 2010, v. 132 n. 50, p. 17646-17648en_HK
dc.identifier.issn0002-7863en_HK
dc.identifier.urihttp://hdl.handle.net/10722/133588-
dc.description.abstractAn unprecedented Au 18 thiacrown directed by Au(I) ···Au(I) interactions and supported by tridentate phosphine (dpepp) and μ 3-sulfido ligands that highly resembles the 18-membered thiacrown ether [18]aneS 6 in appearance has been synthesized. The sulfides of the Au 3(μ 3-S) units in the central cavity point toward each other and are located on the same plane, allowing them to bind the soft Ag + ion with immediate and pronounced spectroscopic changes. Reversible binding and spectroscopic changes can be readily achieved upon addition of CH 3CN without disruption of the Au 18 macrocycle. © 2010 American Chemical Society.en_HK
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.htmlen_HK
dc.relation.ispartofJournal of the American Chemical Societyen_HK
dc.titleAn unprecedented luminescent polynuclear gold(I) μ3-sulfido cluster with a thiacrown-like architectureen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0002-7863&volume=132&issue=50&spage=17646&epage=17648&date=2010&atitle=An+unprecedented+luminescent+polynuclear+gold(I)+μ3-sulfido+cluster+with+a+thiacrown-like+architecture-
dc.identifier.emailZhu, N: nzhu@hkucc.hku.hken_HK
dc.identifier.emailYam, VWW: wwyam@hku.hken_HK
dc.identifier.authorityZhu, N=rp00845en_HK
dc.identifier.authorityYam, VWW=rp00822en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ja1055017en_HK
dc.identifier.pmid21121603-
dc.identifier.scopuseid_2-s2.0-78650259146en_HK
dc.identifier.hkuros185247en_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-78650259146&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume132en_HK
dc.identifier.issue50en_HK
dc.identifier.spage17646en_HK
dc.identifier.epage17648en_HK
dc.identifier.eissn1520-5126-
dc.identifier.isiWOS:000285429800002-
dc.publisher.placeUnited Statesen_HK
dc.relation.projectInstitute of Molecular Functional Materials-
dc.identifier.scopusauthoridLee, TKM=8610515400en_HK
dc.identifier.scopusauthoridZhu, N=7201449530en_HK
dc.identifier.scopusauthoridYam, VWW=18539304700en_HK

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